When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | CH3C(O)O2NO2_Talukdar(1995)_250K_196-344nm(calc).txt |
| NAME: | peroxyacetyl nitrate, PAN |
| FORMULA: | CH3C(O)O2NO2 |
| AUTHOR(YEAR): | Talukdar(1995) |
| T: | 250K |
| λ: | 196-344nm(calc) |
| BIBLIOGRAPHY: |
R.K. Talukdar, J.B. Burkholder, A.-M. Schmoltner, J.M. Roberts, R.R. Wilson, and A.R. Ravishankara, "Investigation of the loss processes for peroxyacetyl nitrate in the atmosphere: UV photolysis and reaction with OH",
J. Geophys. Res. 100(D7), 14163-14173 (1995);
DOI: 10.1029/95JD00545
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| COMMENTS: | Absorption measurements at 250, 273, and 298 K using a diode array spectrometer with a resolution of 0.2 nm The temperature dependence was parameterized to the expression σ(T) = σ(298 K) × exp[B × (T - 298)] The absorption cross sections are calculated using the absorption cross sections measured at 298 K and the temperature coefficients B: -------------------
λ 103 B
(nm) (K-1)
-------------------
196 2.02
198 1.73
200 1.36
202 1.07
203 0.86
206 0.75
208 0.71
210 0.75
212 0.84
214 0.97
216 1.12
218 1.29
220 1.47
222 1.64
224 1.81
226 1.98
228 2.14
230 2.30
232 2.46
234 2.63
236 2.80
238 2.96
240 3.11
242 3.25
244 3.39
246 3.52
248 3.64
250 3.76
252 3.87
254 3.98
256 4.10
258 4.23
260 4.38
262 4.53
264 4.68
266 4.82
268 4.97
270 5.14
272 5.34
274 5.55
276 5.76
278 5.98
280 6.20
282 6.43
284 6.67
286 6.90
288 7.15
290 7.39
292 7.63
294 7.86
296 8.08
298 8.27
300 8.44
302 8.61
304 8.76
306 8.87
308 9.01
310 9.13
312 9.30
314 9.46
316 9.57
318 9.75
320 10.0
322 10.2
324 10.4
326 10.6
328 10.7
330 10.9
332 11.2
334 11.5
336 11.7
338 11.9
340 12.2
342 12.4
344 12.5
324 10.4
326 10.6
328 10.7
330 10.9
332 11.2
334 11.5
336 11.7
338 11.9
340 12.2
342 12.4
344 12.5
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